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This thesisis split into two distinct sections each section corresponding to different heteroallenes ketenimines and keteniminium salts.

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In the first section, diverse strategies were Search Techniques Used By Google Scholar to synthesize ketenimines. Although they are difficult to isolate because of their reactivity; their synthesis was successfully achieved. The idea was to use these highly reactive ketenimines to facilitate Claisen rearrangements, and expand a rearrangement that normally involves ketenes.

This route eventually brought us to another heteroallene source: keteniminium salts. The second section deals with the chemistry of the activation of amides. This chemistry is applied to the generation of a keteniminium salt. Recent works have shown their potential in sigmatropic rearrangements. These works have shown that keteniminium salts could undergo sigmatropic rearrangements with allylic ethers. The idea was to build on this body of work and to further develop the versatility of the method. The author grants permission to the University Librarian at Acadia University to reproduce, loan or distribute copies of my thesis in microform, paper or electronic formats on a non-profit basis.

The author retains the copyright of the thesis.

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Skip to main content. Vinet, L. Search for this publication on Google Scholar. Rights The author grants permission to the University Librarian at Acadia University to reproduce, loan or distribute copies of my thesis in microform, paper or electronic formats on a non-profit basis.]